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World Scientific Series in Contemporary Chemical Physics - Vol. 7

DYNAMIC KERR EFFECT
The Use and Limits of the Smoluchowski Equation and Nonlinear Inertial Responses

by J-L Déjardin (Perpignan Univ.)

This book is conceived as a lecture course on the theory of dielectric and Kerr effect relaxation in molecular fluids. It is based on seminars and lectures to final year graduate students and students preparing for a Ph.D. The book comprises the following: the rotational diffusion equation; perturbative solution obtained from convolution products; Kerr effect response in pulsed electric fields; rotary friction and diffusion coefficients in the case of partial slip conditions; linear detection; electric birefringence in time-varying fields; study of phase angles; the Fokker-Planck–Kramers equation; the role of molecular rotational inertia; and nonlinear dielectric relaxation in coupled electric fields.

The literature on the subject originates essentially from review articles which, however, are pitched at such a high level that it is very difficult for students to understand. Moreover, a lot of details are missing from the calculations in these fundamental papers. This book therefore attempts, in a more didactic manner, to fill these gaps.


Contents:

  • General Forms of Diffusion Equations
  • Analysis of Rotational Molecular Motion in Kerr Effect Relaxation
  • Kerr Effect in Alternating Fields
  • Influence of Molecular Rotational Inertia
  • Nonlinear Response in Dielectric Relaxation
  • Experimental Methods


Readership: Physicists, chemists, electrical engineers and statisticians.


"The book is highly recommended as textbook for graduate students, but as well as monograph for spectroscopists who are interested in the Dynamic Kerr Effect."

F Kremer
Colloid Polym. Sci.




248pp Pub. date: Apr 1995
ISBN 978-981-02-1910-9
981-02-1910-5
US$48 / £34
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Updated on 23 July 2008